Researchers in Korea have developed three-dimensional monolithic corrugated graphene on nickel foam electrode as a Li metal storage framework in carbonate electrolytes. Electrochemical tests reported in their paper in the Journal of Power Sources illustrate the effectiveness of this material design concept, which provides a new route to the development of a Li metal electrode for use in highly reactive electrolytes.
To expedite the commercialization of Li metal anodes by combining them with Li transition metal oxides to achieve a high operating voltage, a carbonate-based electrolyte should be used, which is unstable at low potentials. Therefore, hybrid engineering to prevent dendritic Li growth and increase the coulombic efficiency in highly reactive electrolytes is essential.—Kang et al.
The researchers fabricated the electrode using a simple acid-catalyzed hydrothermal method involving separation of few-layer graphene sheets and formation of corrugated graphene sheets on porous Ni foam.
During the initial Li deposition, Li ions are inserted into the vertical edge plane boundaries between graphene sheets. Li metal deposits then nucleate and grow further underneath the graphene sheets.
Read the full article here:
About the National Graphene Association (NGA)
The National Graphene Association is the main organization and body in the U.S. advocating and promoting the commercialization of graphene. NGA is focused on addressing critical issues such as policy and standards development that will result in effective integration of graphene and graphene based materials globally. NGA brings together current and future graphene stakeholders — entrepreneurs, companies, researchers, developers and suppliers, investors, venture capitalists and government agencies — to drive innovation, and to promote and facilitate the commercialization of graphene products and technologies.